Issue 12, 1976
From the journal:

Journal of the Chemical Society, Dalton Transactions

Perfluoroalkane- and perfluoroarene-thiolates. Part VI. Reactions of some cyclopentadienylnickel derivatives with hexafluorobut-2-yne

John L. Davidson  and  David W. A. Sharp  

Abstract

The reactions of CF3C2CF3 with [{Ni(η-C5H5)(SCF3)}2], [Ni(η-C5H5)2], [Ni(η-C5H5){C5H5(CF3C2CF3)}], [Ni(η-C5H5){C5H5(C2F2Cl)}], and [{Ni(η-C5H5)}2(CF3C2CF3)] have been examined. The new products charscterised are [Ni(η-C5H5){(CF3C2CF3)2H}], [Ni3(η-C5H5)2(CF3C2CF3)3], [Ni2(C5H5)2(CF3C2CF3)3], [Ni(C5H5)2(CF3C2CF3)3], [Ni(η-C5H5){C5H5(CF3C2CF3)2}], [{Ni(C5H5)(CF3C2CF3)}4] and [Ni(C5H5)(CF3C2CF3)2{C5H5(C2CF3Cl)}].

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Article information

DOI
https://doi.org/10.1039/DT9760001123
Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 1123-1129

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Perfluoroalkane- and perfluoroarene-thiolates. Part VI. Reactions of some cyclopentadienylnickel derivatives with hexafluorobut-2-yne

J. L. Davidson and D. W. A. Sharp, J. Chem. Soc., Dalton Trans., 1976, 1123 DOI: 10.1039/DT9760001123

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