E.s.r. and diffuse-reflectance spectra have been obtained for the compounds AgMF6(M = Sn, Ph, Hf, or Zr) and MAgF4(M = Ba, Ca, Hg, or Sr). The data indicate that all the compounds studied contain the silver(II) ion in either an axially elongated tetragonal or a square-planar arrangement. Possible assignments for the electronic-absorption bands are discussed.
G. C. Allen and R. F. McMeeking, J. Chem. Soc., Dalton Trans., 1976, 1063 DOI: 10.1039/DT9760001063
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