Aminodifluorophosphine and boron trifluoride react in the gas or liquid phase to give an adduct, which decomposes into difluoro(difluorophosphinoamino)borane, BF2[NH(PF2)], which has been characterised by mass, photoelectron, n.m.r., and vibrational spectoscopy. With excess of PF2(NH2), the adduct reacts further to give bis(difluorophosphino)amine, NH(PF2)2, and the ammonia–trifluoroborane adduct.
D. E. J. Arnold, E. A. V. Ebsworth and D. W. H. Rankin, J. Chem. Soc., Dalton Trans., 1976, 823 DOI: 10.1039/DT9760000823
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