Issue 3, 1976

The oxidising and fluoride ion acceptor properties of uranium hexafluoride in acetonitrile

Abstract

Metallic copper, cadmium, and thallium are oxidised by uranium hexafluoride in acetonitrile at ambient temperatures to give solutions of copper(II), cadmium(II), and thallium(III) hexafluorouranates(V). After removal of solvent, these salts were obtained as solvates. Copper(II) fluoride reacts with uranium hexafluoride in acetonitrile to give copper(II) heptafluorouranate(VI).

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 272-274

The oxidising and fluoride ion acceptor properties of uranium hexafluoride in acetonitrile

J. A. Berry, R. T. Poole, A. Prescott, D. W. A. Sharp and J. M. Winfield, J. Chem. Soc., Dalton Trans., 1976, 272 DOI: 10.1039/DT9760000272

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