Issue 2, 1976
From the journal:

Journal of the Chemical Society, Dalton Transactions

Transition metal–carbon bonds. Part XXXIX. Carbonylation and nuclear magnetic resonance studies on (α-hydroxyacetylene)bis(triphenylphosphine)platinum complexes

H. David Empsall,   Bernard L. Shaw  and  Alan J. Stringer  

Abstract

New complexes of the type [Pt{R1C⋮CCR2R3(OH)}(PPh3)2](R = H, Ph, or CH2OH) are described. 31P and 1H n.m.r. data are given and the 1H pattern of the methine proton is shown to have more second-order character than previously reported. These complexes carbonylate smoothly to give platinalactone complexes, [[graphic omitted]:CHR1}(PPh3)2], of a new type.

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Article information

DOI
https://doi.org/10.1039/DT9760000185
Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 185-188

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Transition metal–carbon bonds. Part XXXIX. Carbonylation and nuclear magnetic resonance studies on (α-hydroxyacetylene)bis(triphenylphosphine)platinum complexes

H. D. Empsall, B. L. Shaw and A. J. Stringer, J. Chem. Soc., Dalton Trans., 1976, 185 DOI: 10.1039/DT9760000185

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