Issue 2, 1976

Formation constants of chlorocadmium(II) and cadmium dichloride in aqueous melts of calcium dinitrate and calcium dinitrate–potassium nitrate

Abstract

Formation constants of [CdCl]+ and CdCl2 in aqueous melts of Ca[NO3]2·xOH2 and Ca[NO3]2·K[NO3xOH2(x= 3.5–7) have been determined at 50, 65, and 80 °C from e.m.f. measurements in suitable concentration cells. The results are discussed in terms of a quasi-lattice structure of aqueous melts, and a model is proposed which predicts the dependence of thermodynamic data for [CdCl]+ formation on the temperature and water content of the molten salt.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 104-108

Formation constants of chlorocadmium(II) and cadmium dichloride in aqueous melts of calcium dinitrate and calcium dinitrate–potassium nitrate

I. J. Gal, R. M. Nikolić and G. Heraković, J. Chem. Soc., Dalton Trans., 1976, 104 DOI: 10.1039/DT9760000104

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