Crystal structure of tris(diethyldithioby carbamato)iridium(III)

Abstract

The crystal structure of the title compound has been determined by the heavy-atom method from X-ray diffreactometer data, and refined by full-matrix least-squares to R 0.064 for 3 292 observed reflections. Crystals are monoclinic, space group C2/c, and isostructural with the cobalt(III) analogue: a= 14.071(5), b= 10.477(3), c= 16.980(5)Å, β= 108.61 (2)°, Z= 4. Mean Ir–S is 2.36₇Å.