Issue 13, 1976
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel co-ordination of sulphur dioxide. The crystal and molecular structure of nitrosyl(sulphur dioxide)bis(triphenylphosphine)rhodium

David C. Moody  and  R. R. Ryan  

Abstract

Crystals of [Rh(NO)(SO2)(PPh3)2] have been obtained from SO2-saturated solutions of Rh(NO)(PPh3)3 in benzene–heptane mixtures; the X-ray crystal structure shows the SO2 ligand co-ordinated to the rhodium through the sulphur atom and through one of the oxygen atoms, while the RhNO angle is 140°.

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Article information

DOI
https://doi.org/10.1039/C3976000503B
Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 503b-504

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Novel co-ordination of sulphur dioxide. The crystal and molecular structure of nitrosyl(sulphur dioxide)bis(triphenylphosphine)rhodium

D. C. Moody and R. R. Ryan, J. Chem. Soc., Chem. Commun., 1976, 503b DOI: 10.1039/C3976000503B

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