(Nitric oxide) tetraphenylporphyrincobalt, [Co(TPP)(NO)], is found to add nitric oxide sequentially to form an S= 1/2 complex [Co(TPP)(NO)2] and a diamagnetic species tentatively formulated as [Co(TPP)(NO)(N2O2)].
B. B. Wayland and J. V. Minkiewicz, J. Chem. Soc., Chem. Commun., 1976, 1015 DOI: 10.1039/C39760001015
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