Defluorination of pentafluorosulphur chloride and pentafluorosulphur bromide by strong nucleophiles
Abstract
Strong nucleophiles, (CF3)2C
NLi and (CH3)2-NSi(CH3)3, readily defluorinate SF5Cl and SF5Br to form SF3X
NCF(CF3)2, SFX[
NCF(CF3)2]2, and trans-(CH3)2-NSF4X (X = Cl,Br).
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