SCHEDULED MAINTENANCE
The bridgehead proton hyperfine splitting constant of the bicyclo[2.1.1]hexan-1-yl radical is unexpectedly large (22.49 G); INDO calculations show that this is due to ‘through-space’ as well as ‘through-bond’ spin transfer from C–1 to 4–H.
T. Kawamura and T. Yonezawa, J. Chem. Soc., Chem. Commun., 1976, 948 DOI: 10.1039/C39760000948
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