Reaction of [Ru3(CO)12] with [Mn(CO)5]– gives [Ru6(CO)18]2– which on acidification is converted into [HRu6(CO)18]–; this monoanion has spectroscopic properties and an X-ray structure consistent with the H ligand lying at the centre of an octahedron (approximating to Oh symmetry) of ruthenium atoms.
C. R. Eady, B. F. G. Johnson, J. Lewis, M. C. Malatesta, P. Machin and M. McPartlin, J. Chem. Soc., Chem. Commun., 1976, 945 DOI: 10.1039/C39760000945
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