Issue 21, 1976
From the journal:

Journal of the Chemical Society, Chemical Communications

X-Ray structures of the hexanuclear cluster complexes [Os6(CO)18]2–, [HOs6(CO)18]–, and [H2Os6(CO)18]

Mary McPartlin,   Colin R. Eady,   Brian F. G. Johnson  and  Jack Lewis  

Abstract

X-Ray analyses of three osmium cluster complexes has shown that two, [Os6(CO)18]2– and [HOs6-(CO)18]–, have the approximately regular octahedral structure expected for hexanuclear clusters with 86 valence electrons, but the third, [H2Os6(CO)18], has an unusual monocapped square-pyramidal Os6 arrangement.

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Article information

DOI
https://doi.org/10.1039/C39760000883
Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 883-885

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X-Ray structures of the hexanuclear cluster complexes [Os6(CO)18]2–, [HOs6(CO)18]–, and [H2Os6(CO)18]

M. McPartlin, C. R. Eady, B. F. G. Johnson and J. Lewis, J. Chem. Soc., Chem. Commun., 1976, 883 DOI: 10.1039/C39760000883

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