trans-2-Methylcyclopropyl(stannyloxy or hydroxy)methyl radicals undergo ring-opening to give principally the thermodynamically less stable primary alkyl radicals; use has been made of this effect to establish the conditions under which the cyclopropylmethyl → homo-allyl rearrangement is reversible.
A. G. Davies, J. Godet, B. Muggleton and M. Pereyre, J. Chem. Soc., Chem. Commun., 1976, 813 DOI: 10.1039/C39760000813
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