The phosphazenes [NP(NHMe)2]n, [NP(NHMe)2]4, and [NPMe2]4, react with K2PtCl4 in organic media to yield square-planar Pt complexes of the type (NPR2)x PtCl2, and in aqueous acid media to yield salts of the type, [H2N4P4R8]2+[PtCl4]2–; moreover, these compounds have shown significant antitumour behaviour in preliminary testing.
H. R. Allcock, R. W. Allen and J. P. O'Brien, J. Chem. Soc., Chem. Commun., 1976, 717 DOI: 10.1039/C39760000717
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