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γ-Radiolysis of liquid CO2 and PhC![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CR (1) in the presence of methanol gives PhCH(OMe)COR (5) and PhRCHCO2Me (6), indicating the formation of an α-ketocarbene (2) by the attack of O(3P), generated by γ-radiolysis of liquid CO2, on the phenylacetylene.
A. Hori, S. Takamuku and H. Sakurai, J. Chem. Soc., Chem. Commun., 1976, 686 DOI: 10.1039/C39760000686
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