In the decomplexation reaction of the tricarbonyl iron complex of 2,5-dimethylthiophen SS-dioxide by trimethylamine oxide in an aprotic solvent an intermediate containing a protonated dimethylamino-ligand has been isolated and idntified.
J. H. Eekhof, H. Hogeveen and R. M. Kellogg, J. Chem. Soc., Chem. Commun., 1976, 657 DOI: 10.1039/C39760000657
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