Issue 16, 1976

Metallation of weak hydrocarbon acids by potassium hydride–18-crown-6 polyether in tetrahydrofuran and the relative acidity of molecular hydrogen

Abstract

Potassium hydride in tetrahydrofuran in the presence of 18-crown-6 polyether is capable of metallating the hydrocarbons triphenylmethane, diphenylmethane, di-p-tolymethane (to completion), and di-2,4-xylyl-methane (partial completion); the results allow an estimate of the relative acidity of hydrogen with respect to the hydrocarbons studied.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 648-649

Metallation of weak hydrocarbon acids by potassium hydride–18-crown-6 polyether in tetrahydrofuran and the relative acidity of molecular hydrogen

E. Buncel and B. Menon, J. Chem. Soc., Chem. Commun., 1976, 648 DOI: 10.1039/C39760000648

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