Issue 15, 1976

Reaction of keten dithio-acetals with aziridine. Iodide ion-catalysed rearrangement of thio-aziridino-methylene compounds to novel Δ1-2-methylthio-3,3-disubstituted pyrrolines

Abstract

The keten dithioacetals (1) and (5) react readily with aziridine (2) to give the corresponding thioaziridinemethylene compounds (3) and (6) respectively, which on iodide ion-catalysed rearrangement, undergo ring expansion to give the pyrrolines (4) and (7) respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 592-593

Reaction of keten dithio-acetals with aziridine. Iodide ion-catalysed rearrangement of thio-aziridino-methylene compounds to novel Δ1-2-methylthio-3,3-disubstituted pyrrolines

A. Kumar, H. Ila, H. Junjappa and S. Mhatre, J. Chem. Soc., Chem. Commun., 1976, 592 DOI: 10.1039/C39760000592

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