The 13C-n.m.r. spectrum of glauconic acid (I) enriched with [2,3-13C]succinate shows only two paris of 13C–13C couplings indicating incorporation into the oxalacetate-derived residue but no detectable incorporation into the β-ketide derived fragment via the expected degradation product [1,2-13C]acetate.
R. E. Cox and J. S. E. Holker, J. Chem. Soc., Chem. Commun., 1976, 583 DOI: 10.1039/C39760000583
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