The sodium salt of benzaldoxime and phenyl isothiocyanate give the corresponding O-[(p-tolyl)thiocarbamoyl]oxime which spontaneously eliminates benzonitrile at least partly by a radical-cage mechanism.
R. F. Hudson and K. A. F. Record, J. Chem. Soc., Chem. Commun., 1976, 539 DOI: 10.1039/C39760000539
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