Issue 14, 1976

Crystal and molecular structure of the five-co-ordinate, S[double bond, length half m-dash]1, macrocyclic complex of cobalt(III), [Co(C22H22N4)I]·CHCl3: 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetra-azacyclotetradecinato(iodo)cobalt(III) iodide

Abstract

The X-ray crystal structure and its implications in chemical reactivity of a novel five-co-ordinate macrocyclic complex of cobalt(III), [Co(C22H22N4)I]·CHCl3, having an S= 1 ground state are described.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 531-532

Crystal and molecular structure of the five-co-ordinate, S[double bond, length half m-dash]1, macrocyclic complex of cobalt(III), [Co(C22H22N4)I]·CHCl3: 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetra-azacyclotetradecinato(iodo)cobalt(III) iodide

M. C. Weiss and V. L. Goedken, J. Chem. Soc., Chem. Commun., 1976, 531 DOI: 10.1039/C39760000531

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