It is shown by 19F and 1H n.m.r. spectroscopy that the complex MeF–SbF5 does not exist in solution in SO2, as the solvent is methylated with the formation of CH3OSO+, but it can be obtained in SO2F2 as a stable species which undergoes neither intramolecular nor inter-molecular exchange on the n.m.r. time scale.
J. Calves and R. J. Gillespie, J. Chem. Soc., Chem. Commun., 1976, 506 DOI: 10.1039/C39760000506
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