Determinations of the vertical ionization potentials by He I photoelectron spectroscopy and the rates of electrophilic cleavage of exo- and endo-2-norbornyl-methylmercury are consistent with enhanced σ-participation as a mode of charge delocalization in the exo epimer.
W. A. Nugent, M. M.-H. Wu, T. P. Fehlner and J. K. Kochi, J. Chem. Soc., Chem. Commun., 1976, 456 DOI: 10.1039/C39760000456
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