With cycloheX-2-enones, methyl α-bromocrotonate undergoes double Michael additions and subsequent substitution yielding tricyclo[3.2.1.02,7]octan-6-ones in one-step.
H. Hagiwara, T. Kodama, H. Kosugi and H. Uda, J. Chem. Soc., Chem. Commun., 1976, 413 DOI: 10.1039/C39760000413
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