Tetrakis(dimethoxyboryl)silane has been synthesized from silicon tetrachloride, lithium, and dimethoxyboron chloride, and the boron-silicon bonds have been found highly susceptible to oxidative or hydrolytic cleavage, yet sufficiently stable to survive transesterification of the boronic ester with ethylene glycol.
R. J. Wilcsek, D. S. Matteson and J. G. Douglas, J. Chem. Soc., Chem. Commun., 1976, 401 DOI: 10.1039/C39760000401
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