A trigonal prismatic vanadium(IV) complex: bis(acetylacetone benzoylhydrazonato)vanadium(IV); X-ray crystal structure
Abstract
Reaction of benzoylhydrazine with bis(acetylacetonato)oxovanadium(IV) leads to polymeric vanadium-(V) complexes as well as a monomeric bis(tridentate)-vanadium(IV) complex which has trigonal prismatic co-ordination and which does not contain an oxo-ligand.