Oxidative additions of 7,8- and 7,9-C2B9H12– to [(PPh3)3RuHCl] have yielded novel dihydro-ruthenium complexes 3,1,2- and 2,1,7-[(PPh3)2RuH2C2B9H11] respectively; the latter's structure has been comfirmed by X-ray diffraction study and it has been found reversibly to eliminate its hydride ligands as H2upon heating in vacuo.
E. H. S. Wong and M. F. Hawthorne, J. Chem. Soc., Chem. Commun., 1976, 257 DOI: 10.1039/C39760000257
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