Position of bond cleavage in the acid-catalysed hydrolysis of methyl methylarylphosphinates
Abstract
The hydrolysis of methyl methylarylphosphinate esters in 1·0 M HClO4 at 67 °C is found to proceed with ca. 90% P–O and 10% C–O bond fission.
The hydrolysis of methyl methylarylphosphinate esters in 1·0 M HClO4 at 67 °C is found to proceed with ca. 90% P–O and 10% C–O bond fission.
R. A. McClelland, J. Chem. Soc., Chem. Commun., 1976, 226 DOI: 10.1039/C39760000226
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