Structural models for the co-ordination geometries of a CuI–CuII redox couple in copper enzymes have been prepared and characterized; they suggest a mechanism for certain copper enzyme reactions where both electrons and protons are involved.
H. Henriksson, B. Sjöberg and R. Österberg, J. Chem. Soc., Chem. Commun., 1976, 130 DOI: 10.1039/C39760000130
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