Although methanolysis of 5-chloromethyl-5-methyl-2-oxo-2-phenylthio-1,3,2-dioxaphosphorinan under normal conditions proceeds with retention of configuration at phosphorus, in the presence of cations capable of co-ordinating with sulphur, both inversion and retention pathways are observed.
W. S. Wadsworth and R. L. Wilde, J. Chem. Soc., Chem. Commun., 1976, 93 DOI: 10.1039/C39760000093
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