Rearrangement of syn- and anti-7-vinylbicyclo-[4.1.0]heptanes in the presence of di-µ-chloro-tetra-carbonyldirhodium(I) exhibits kinetic behaviour and product selectivity which provide good evidence for initial co-ordination of the vinyl group and stereospecific cis-β-hydride elimination from a subsequent metallocyclic intermediate.
M. F. Salomon and R. G. Salomon, J. Chem. Soc., Chem. Commun., 1976, 89 DOI: 10.1039/C39760000089
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