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With 3,7-dimethylocta-1,6-diene, carbon radicals ·CH2CO2H, ·CH(COMe)2, and ·CH(COMe)CO2Et add at the 6,7-alkene bond, whilst ·CH2COR(R = Me,Ph), ·CH(CO2Me)2, oxocyclopentyl, and oxocyclohexyl react at the 1,2-alkene; it is suggested that this behaviour is indicative of reversible addition at the 6,7 positions by the second group of radicals.
F. J. McQuillin and M. Wood, J. Chem. Soc., Chem. Commun., 1976, 65 DOI: 10.1039/C39760000065
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