A series of triple chloro-bridged heterobimetallic phosphine complexes of the type [(PPh3)LClRuCl3RhClL2](L = PMe2Ph, PEt2Ph, PBun2Ph, PBun3, or PPh3) have been prepared from the mononuclear complexes [RuCl2(PPh3)3] and [RhCl3L3]; these reactions involve phosphine–ligand transfer from rhodium to ruthenium.
R. A. Head and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1976, 62 DOI: 10.1039/C39760000062
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