Experiments showing positive incorporation of [14C]-p-benzoquinone into luciferin strongly suggest that the benzothiazole nucleus in firefly luciferin arises from p-benozquinone and cysteine.
K. Okada, H. Iio and T. Goto, J. Chem. Soc., Chem. Commun., 1976, 32 DOI: 10.1039/C39760000032
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