The equilibrium constants for the addition of the nitrosonium ion to the sulphur atom of a range of alkylthioureas have been measured, and shown to correlate well with the ionisation constants of the corresponding conjugate acids. Stopped-flow studies of the rate of reaction show it to occur by an encounter-controlled process.
P. Collings, K. Al-Mallah and G. Stedman, J. Chem. Soc., Perkin Trans. 2, 1975, 1734 DOI: 10.1039/P29750001734
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