Issue 13, 1975

Investigation of photolysis of o-nitrophenols by electron spin resonance spectroscopy. Characterisation of 1,2-benzoquinone monohydroxyimine free radicals

Abstract

The photolysis of tetrahydrofuran (THF) solutions containing o-nitrophenols and di-t-butyl peroxide (DTBP) has been examined by e.s.r. spectroscopy. In carefully degassed solutions a series of 1,2-benzoquinone monohydroxyimine free radicals are formed, the structures of which have been confirmed using an unambiguous synthesis by oxidation of appropriate nitrosophenols in a flow system. The origin of hyperfine splittings is such radicals has been evaluated. Structures are tentatively proposed for free radicals observed during the photolysis of inefficiently degassed THF solutions of o-nitrophenols and DTBP; the same radicals are obtained when analogous nitrosophenols are photolysed under identical conditions.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1975, 1380-1384

Investigation of photolysis of o-nitrophenols by electron spin resonance spectroscopy. Characterisation of 1,2-benzoquinone monohydroxyimine free radicals

R. G. Green, L. H. Sutcliffe and P. N. Preston, J. Chem. Soc., Perkin Trans. 2, 1975, 1380 DOI: 10.1039/P29750001380

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