Infrared intensities as a quantitative measure of intramolecular interactions. Part XLII. 1,2-Disubstituted ethylenes
Abstract
Infrared intensities of cis- and trans-1,2-disubstituted ethylenes indicate that interactions between substituents are qualitatively similar to but quantitatively 1.5 times those in the corresponding para-disubstituted benzenes. Successful calculations of the dipole transition moments from CNDO/2 molecular orbital theory are presented.
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