Rate constants of hydrolysis for 4-chloro-N-n-propyl- and N-isobutyl-benzamides have been measured in sulphuric acid at 100.7°. Existing criteria of mechanism have been applied to the rate data. Taft parameters have been applied to the chemical shifts, δNH, the basicity constants, KBH+, and the rate constants of hydrolysis, Kψ, in sulphuric acid at 100.7° of a series of N-alkyl-4-chlorobenzamides.
C. J. Giffney (née Hyland) and C. J. O'Connor, J. Chem. Soc., Perkin Trans. 2, 1975, 1203 DOI: 10.1039/P29750001203
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