SCHEDULED MAINTENANCE
The basicity constants, KBH+, of 13 acetanilides have been evaluated in sulphuric acid at 25°. Recent evidence on the site of protonation of amides has been reviewed and a new equation for calculating pKBH+ has been formulated. The values of pKBH+ obtained for the para-substituted acetanilides correlate well with Hammett σ values.
C. J. Giffney (née Hyland) and C. J. O'Connor, J. Chem. Soc., Perkin Trans. 2, 1975, 706 DOI: 10.1039/P29750000706
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