Radicals which mediate in the reactions of aliphatic carboxylate ions with the sulphate radical-anion, generated from the TiIII–K2S2O8 couple, have been observed by e.s.r. spectroscopy. Both oxidative decarboxylation (RCO2–→ R˙) and hydrogen-atom abstraction from C–H occur. The behaviour of SO4–˙ is compared with that of ·OH.
W. C. Vasudeva, J. Chem. Soc., Perkin Trans. 2, 1975, 697 DOI: 10.1039/P29750000697
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