In the presence of certain paramagnetic ions the transverse relation times (T2), readily available from half-width measurements, provide a sensitive probe to molecular structure. Protons closest to the metal ion are preferentially broadened and this is used to assign resonances.
G. V. Fazakerley and G. E. Jackson, J. Chem. Soc., Perkin Trans. 2, 1975, 567 DOI: 10.1039/P29750000567
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