Issue 4, 1975

Conformations of some αβ-unsaturated carbonyl compounds. Part VI. Comparison of out-of-plane olefinic CH deformation vibrations

Abstract

A comparison is made between the corresponding out-of-plane CH deformation modes in the compounds CH2:CMe·CO·OX, CH2:CHCO·OX, and MeCH:CH·CO·OX for nine different substituents X. The results provide reinterpretations of assignments, evidence of interactions between modes of a type in contrast to any expected resonance interactions, and some new considerations of conformational equilibria.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1975, 396-400

Conformations of some αβ-unsaturated carbonyl compounds. Part VI. Comparison of out-of-plane olefinic CH deformation vibrations

J. R. Cowles, W. O. George and W. G. Fateley, J. Chem. Soc., Perkin Trans. 2, 1975, 396 DOI: 10.1039/P29750000396

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