Issue 4, 1975

Nuclear magnetic resonance conformational studies of C-substituted pyrrolecarbaldehydes. Part II. Barrier to internal rotation in 5-substituted pyrrole-2-carbaldehydes

Abstract

A study of the variations of the n.m.r. spectra of ethyl 5-formylpyrrole-2-carboxylate and pyrrole-2,5-dicarbaldehyde with temperature allowed a determination of the activation parameters by lineshape analysis of the formyl signals. The influence of the nature of the substituent on the spectrum is considered.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1975, 337-340

Nuclear magnetic resonance conformational studies of C-substituted pyrrolecarbaldehydes. Part II. Barrier to internal rotation in 5-substituted pyrrole-2-carbaldehydes

M. Farnier and T. Drakenberg, J. Chem. Soc., Perkin Trans. 2, 1975, 337 DOI: 10.1039/P29750000337

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