Issue 23, 1975

Polyfluoroarenes. Part XXI. Synthesis, decarbonylation, and dehydration of 2′,3′,4′,5′,6′-pentafluoroformanilide: formation of pentafluoro-phenyl isocyanide

Abstract

Pentafluoroformanilide has been synthesised from ethyl formate and the monosodium salt of pentafluoroaniline; its spectroscopic properties are discussed, and its decarbonylation to pentafluoroaniline with hot calcium oxide and dehydration to pentafluorophenyl isocyanide with phosphorus pentaoxide at 250 °C are described.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1975, 2451-2454

Polyfluoroarenes. Part XXI. Synthesis, decarbonylation, and dehydration of 2′,3′,4′,5′,6′-pentafluoroformanilide: formation of pentafluoro-phenyl isocyanide

R. E. Banks, R. N. Haszeldine and B. G. Willoughby, J. Chem. Soc., Perkin Trans. 1, 1975, 2451 DOI: 10.1039/P19750002451

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