2-Methyl-3-methylamino-2-azabicyclo[3.2.1]oct-6-ene (4) has been prepared and shown to coexist with N-methyl-4-(2-methyliminoethyl)cyclopent-2-enylamine (3). This material behaves as the gem-diamine (4) on catalytic reduction and as the imine (3) on reduction with metal hydrides. A useful method of synthesising cis-3,5-disubstituted cyclopentenes is reported.
P. Barraclough and D. W. Young, J. Chem. Soc., Perkin Trans. 1, 1975, 2354 DOI: 10.1039/P19750002354
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