The stereochemistry of the allylic alcohol (2) and of the epoxy-ketone (3) in the Westphalen-type rearranged steroid series has been elucidated. The n.m.r. spectra of various new and known compounds have been analysed, thus demonstrating the remarkable conformational flexibility of ring B in this series.
E. Glotter, Y. Rabinsohn and Y. Ozari, J. Chem. Soc., Perkin Trans. 1, 1975, 2104 DOI: 10.1039/P19750002104
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