Issue 20, 1975

Determination of the stereochemistry of the product of rearrangement of penicillin G with methyl chloroformate by total synthesis

Abstract

Separate stereospecific syntheses of the product [4-isopropylidene-2-(2-methylthio-1-phenylacetamidovinyl)-oxazol-5-(4H)-one] from the rearrangement of penicillin G with methyl chloroformate and of its geometric isomer have defined the former as the Z-isomer.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1975, 2086-2091

Determination of the stereochemistry of the product of rearrangement of penicillin G with methyl chloroformate by total synthesis

C. J. Veal and D. W. Young, J. Chem. Soc., Perkin Trans. 1, 1975, 2086 DOI: 10.1039/P19750002086

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