The positions of labelled atoms in fusicoccin biosynthesised from [1-13C]- and [2-13C]-acetate have been determined by 13C n.m.r. spectroscopy. The results are consistent with fusicoccin being formed by direct cyclisation of a precursor such as geranylgeraniol pyrophosphate.
K. D. Barrow, R. B. Jones, P. W. Pemberton and L. Phillips, J. Chem. Soc., Perkin Trans. 1, 1975, 1405 DOI: 10.1039/P19750001405
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