Issue 14, 1975

Oxidation of some trinuclear aromatic compounds with cerium(IV) ammonium nitrate

Abstract

Anthrone, xanthen, and thioxanthen were oxidised with cerium(IV) ammonium nitrate (CAN) in methanol to yield anthraquinone, xanthone, and thioxanthone. In methanol, acridine gave acridine and small amounts of 3-nitro-and 3,7-dinitro-acridone; phenazine gave the mono-N-oxide. Oxidation of acridine or acridone in acetic acid at reflux temperature gave 1,3,7-trinitro- and 1,3,7,9-tetranitro-acridone.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1975, 1398-1400

Oxidation of some trinuclear aromatic compounds with cerium(IV) ammonium nitrate

B. Rindone and C. Scolastico, J. Chem. Soc., Perkin Trans. 1, 1975, 1398 DOI: 10.1039/P19750001398

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